Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/19664
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dc.contributor.authorAl Hareri, M.pt
dc.contributor.authorGavey, E. L.pt
dc.contributor.authorRegier, J.pt
dc.contributor.authorAli, Z. Raspt
dc.contributor.authorCarlos, L. D.pt
dc.contributor.authorFerreira, R. A. S.pt
dc.contributor.authorPilkington, M.pt
dc.date.accessioned2017-12-07T19:20:42Z-
dc.date.issued2016pt
dc.identifier.issn1359-7345pt
dc.identifier.urihttp://hdl.handle.net/10773/19664-
dc.description.abstractThe first supramolecular cage formed by three benzo-15-crown-5 macrocycles encapsulating a [Dy(OH2)(8)](3+) guest cation is reported, with the Dy(III) centre exhibiting local pseudo square antiprismatic D-4d symmetry. The anisotropy barrier extracted from ac susceptibility studies, emission spectroscopy and ab initio calculations reveals that the second excited state Kramers doublet plays a key role in the magnetization dynamics due to the Ising character and near coparallel nature of the ground and first excited Kramers doublets.pt
dc.language.isoengpt
dc.publisherROYAL SOC CHEMISTRYpt
dc.relationinfo:eu-repo/grantAgreement/FCT/5876/147332/PTpt
dc.rightsrestrictedAccesspor
dc.subjectSINGLE-MOLECULE MAGNETSpt
dc.subjectION-MAGNETpt
dc.subjectDY-IIIpt
dc.subjectRELAXATION DYNAMICSpt
dc.subjectOPTICAL-PROPERTIESpt
dc.subjectSLOW RELAXATIONpt
dc.subjectZN-DYpt
dc.subjectCOMPLEXpt
dc.subjectANISOTROPYpt
dc.subjectSYMMETRYpt
dc.titleEncapsulation of a [Dy(OH2)(8)](3+) cation: magneto-optical and theoretical studies of a caged, emissive SMMpt
dc.typearticlept
dc.peerreviewedyespt
ua.distributioninternationalpt
degois.publication.firstPage11335pt
degois.publication.issue76pt
degois.publication.lastPage11338pt
degois.publication.titleCHEMICAL COMMUNICATIONSpt
degois.publication.volume52pt
dc.date.embargo10000-01-01-
dc.relation.publisherversion10.1039/c6cc03578gpt
dc.identifier.doi10.1039/c6cc03578gpt
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