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|Title:||Why is the CO2-CS2 non-ideality larger than in CO2-CCl4? A Raman scattering study|
Cabaco, M. I.
Coutinho, J. A. P.
|Publisher:||ELSEVIER SCIENCE BV|
|Abstract:||The dense phases of the CO2-CCl4 (I) and CO2-CS2 (II) mixtures have been studied by Raman spectroscopy. Mixture I is found almost ideal and II strongly non-ideal. At high CS2 concentration in II, the local structure of CS2 is preserved suggesting a nano-segregation of the liquid phase without demixing whereas in CO2 concentrated mixtures a diversity of species are present. Thermodynamical considerations together with spectroscopic results show that a subtle interplay between attractive and repulsive interactions leads to this non-ideal behaviour. The connection of these results with the liquid-liquid demixing reported for CO2-CS2 at lower temperature is discussed. (C) 2013 Elsevier B. V. All rights reserved.|
|Appears in Collections:||CICECO - Artigos|
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|Why is the CO2-CS2 non-ideality larger than in CO2-CCl4 A Raman scattering study_10.1016j.cplett.2013.07.061.pdf||229.53 kB||Adobe PDF||Request a copy|
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