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|Title:||New Cu3TeO6 Ceramics: Phase Formation and Dielectric Properties|
Vilarinho, Paula M.
|Publisher:||AMER CHEMICAL SOC|
|Abstract:||Targeting low temperature cofired ceramics (LTCC) applications and base-metal electrode multilayer ceramic capacitors (BME-MLCCs), ceramics of a new composition, tricopper tellurate (Cu3TeO6), are reported here. The crystal structure of Cu3TeO6 was determined to be cubic, Ia3, with the unit cell parameter a = 9.538 angstrom. The sequence of phase formation is proposed with the oxidation of tetravalent tellurium (Te4+) into hexavalent tellurium (Te6+) as a key step for the formation of Cu3TeO6. Ceramics sintered at 865 degrees C with densities of 94% exhibit two dielectric anomalies in the temperature dependence of the dielectric response, around -150 degrees C and +50 degrees C, respectively, accompanied by obvious frequency dispersion of the relative permittivity (epsilon(r)) and dielectric losses (tan delta), with an Arrhenius like behavior. A temperature stable dielectric region (near room temperature) formed between the two anomalies with epsilon(r) similar to 12 and tan delta similar to 0.01, and a very low positive temperature coefficient of the relative permittivity (TC epsilon(r)), 2.07 X 10(-4) degrees C-1, was obtained in the same region. The low temperature dielectric anomaly is associated with the possible mixed Cu+/Cu2+ valence in Cu3TeO6 ceramics, while the high temperature anomaly is attributed to point defect ordering, including V-O, Cu-Cu2+(+)',which might be formed during sintering. Therefore, Cu3TeO6 ceramics are of interest in view of not only the possible applications in BME-MLCCs, LTCC, and related technologies, but also for their possible compatibility with low cost abundant Cu electrodes.|
|Appears in Collections:||CICECO - Artigos|
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|New Cu 3TeO 6Ceramics Phase Formation and Dielectric Properties_10.1021am501742z.pdf||3.53 MB||Adobe PDF|
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