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Title: | Six new 3d-4f heterometallic coordination polymers constructed from pyrazole-bridged Cu(II)Ln(III) dinuclear units |
Author: | Yang, Ting-Hai Silva, Ana Rosa Shi, Fa-Nian |
Keywords: | METAL-ORGANIC FRAMEWORKS SINGLE-MOLECULE MAGNET INORGANIC SUBNETWORK COMPLEXES LIGAND CLUSTERS LN RELAXATION CATALYSIS SULFATE |
Issue Date: | 2013 |
Publisher: | ROYAL SOC CHEMISTRY |
Abstract: | Reactions of lanthanide chlorides, copper hydroxycarbonate and 3,5-pyrazole dicarboxylic acid (H(3)pdc) under hydrothermal conditions result in six new 3d-4f heterometallic coordination polymers with two types of structures. Compounds [CuLn(2)(pdc)(2)(Hpdc)(H2O)(4)]center dot 2H(2)O (Ln = Tb (1), Dy (2), Er (3), and Y (4) exhibit a layered porous structure, made up of Cu(II)Ln(III) di-nuclear units which are connected by protonated Hpdc(2-) ligand, while the others [Cu(3)Ln(4)(pdc)(6)(H2O)(8)] (Ln = Eu (5), Gd (6)) display a three-dimensional (3-D) framework structure, in which six Cu(II)Ln(III) di-nuclear units are cross-linked by two coordinated lanthanide atoms. The catalytic properties of 3 are investigated showing its activity and recyclability in the reaction of cyclopropanation of styrene. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19289 |
DOI: | 10.1039/c3dt51015h |
ISSN: | 1477-9226 |
Publisher Version: | 10.1039/c3dt51015h |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Six new 3d–4f heterometallic coordination polymers constructed from pyrazole-bridged CuIILnIII dinuclear units_10.1039c3dt51015h.pdf | 2.71 MB | Adobe PDF |
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