Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/19254
Title: Crystal structures of the water and acetone monosolvates of bis[4 '-(pyridin-4-yl)-2,2 ':6 ',2 ''-terpyridine]manganese(II) bis(hexafluoridophosphate)
Author: Lourenco, Leandro M. O.
Almeida Paz, Filipe A.
Fernandes, Jose A.
Keywords: EXPANDED 4,4'-BIPYRIDINE LIGAND
COORDINATION POLYMERS
COMPLEXES
PYTPY=4'-(4-PYRIDYL)-2,2'/6',2''-TERPYRIDINE
METALLOLIGAND
Issue Date: 2015
Publisher: INT UNION CRYSTALLOGRAPHY
Abstract: The crystal structures of bis[4'-(pyridin-4-yl)-2,2':6',2 ''-terpyridine]manganese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C20H14N4)(2)](PF6)(2)center dot-H2O, (1), and bis[4'-(pyridin-4-yl)-2,2':6',2 ''-terpyridine]manganese(II) bis-(hexafluoridophosphate) acetone monosolvate, (2), [Mn(C20H14N4)(2)]-(PF6)(2)center dot CH3COCH3, are described. At 150 K, (1) and (2) have monoclinic (P2(1)/c) and orthorhombic (C222(1)) symmetries, respectively. Both structures exhibit octahedrally coordinated Mn-II atoms and disorder. They display weak interactions, such as C-H center dot center dot center dot F, C-H center dot center dot center dot N, C-H center dot center dot center dot pi, F center dot center dot center dot pi and pi-pi. The twofold rotation axis in the molecule of (2) is coincident with a twofold rotation axis of the crystal.
Peer review: yes
URI: http://hdl.handle.net/10773/19254
DOI: 10.1107/S2056989015003503
ISSN: 2056-9890
Publisher Version: 10.1107/S2056989015003503
Appears in Collections:CICECO - Artigos



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