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http://hdl.handle.net/10773/19215
Título: | Low-temperature dielectric relaxations in Y-doped strontium titanate ceramics |
Autor: | Tkach, Alexander Vilarinho, Paula M. Almeida, Abilio |
Palavras-chave: | OXIDE FUEL-CELLS ELECTRICAL-CONDUCTIVITY ANODE MATERIALS SRTIO3 MICROSTRUCTURE SPECTROSCOPY BI-SRTIO3 RELAXOR |
Data: | 2015 |
Editora: | IOP PUBLISHING LTD |
Resumo: | The structural and low-frequency dielectric properties of Y-doped strontium titanate ceramics prepared by the conventional mixed oxide method are investigated. The lattice parameter is found to decrease linearly in the Sr1-1.5xYxTiO3 system, confirming the incorporation of Y onto the Sr site of perovskite lattice of strontium titanate up to the solid solubility limit below x = 0.05. The real and imaginary parts of the dielectric permittivity of Sr1-1.5xYxTiO3 ceramics exhibit a relaxation between 100 Hz and 1 MHz in the temperature range 10-40 K, slightly shifting to higher temperatures with increasing Y content. Such dielectric behavior, yielding real part of the dielectric permittivity up to 35 000, is attributed to the relaxation of individual dipoles formed by off-center displacement of Y3+ ions on Sr sites in a highly polarizable lattice of strontium titanate. The other dielectric relaxation observed in Sr1-1.5xYxTiO3 from 125 to 300 K is attributed to the oxygen vacancy related mechanisms. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19215 |
DOI: | 10.1088/0022-3727/48/8/085302 |
ISSN: | 0022-3727 |
Versão do Editor: | 10.1088/0022-3727/48/8/085302 |
Aparece nas coleções: | CICECO - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Low-temperature dielectric relaxations in Y-doped strontium titanate ceramics_10.10880022-3727488085302.pdf | 743.91 kB | Adobe PDF |
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