Utilize este identificador para referenciar este registo:
http://hdl.handle.net/10773/19178
Título: | A 2D -> 3D Polycatenated Metal-Organic Framework: Synthesis, Structure, Magnetic and Catalytic Study |
Autor: | Sen, Rupam Saha, Debraj Mal, Dasarath Brandao, Paula Rogez, Guillaume Lin, Zhi |
Palavras-chave: | MOLECULAR-OXYGEN COORDINATION POLYMERS HYDROGEN-PEROXIDE ASYMMETRIC DIHYDROXYLATION SELECTIVE OXIDATION ALKENE EPOXIDATION OLEFIN EPOXIDATION PRACTICAL METHOD ACTIVATION COMPLEXES |
Data: | 2013 |
Editora: | WILEY-V C H VERLAG GMBH |
Resumo: | A mixed-ligand 3D metal-organic framework, [Ni(1,2-cpd)(bpe)(H2O)]n (1) [1,2-cpd = cis-cyclopentane-1,2-dicarboxylate, bpe = 1,2-di(4-pyridyl)ethylene], has been constructed. Topological analysis revealed that the structure is a 3-c uninodal 2D + 2D 3D polycatenated net with the Schlafli symbol 63. The compound is catalytically active towards the epoxidation reaction in heterogeneous media. It catalyses almost all types of olefinic substrates with equal efficiency. After reaction it can be recovered quite easily and can be used for further reaction without any loss of activity for several cycles. Variable-temperature magnetic susceptibility measurement reveals the presence of a weak antiferromagnetic interaction in compound 1. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19178 |
DOI: | 10.1002/ejic.201300123 |
ISSN: | 1434-1948 |
Versão do Editor: | 10.1002/ejic.201300123 |
Aparece nas coleções: | CICECO - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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A 2D → 3D polycatenated metal-organic framework Synthesis structure magnetic and catalytic study_10.1002ejic.201300123.pdf | 452.04 kB | Adobe PDF |
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