Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/19178
Title: A 2D -> 3D Polycatenated Metal-Organic Framework: Synthesis, Structure, Magnetic and Catalytic Study
Author: Sen, Rupam
Saha, Debraj
Mal, Dasarath
Brandao, Paula
Rogez, Guillaume
Lin, Zhi
Keywords: MOLECULAR-OXYGEN
COORDINATION POLYMERS
HYDROGEN-PEROXIDE
ASYMMETRIC DIHYDROXYLATION
SELECTIVE OXIDATION
ALKENE EPOXIDATION
OLEFIN EPOXIDATION
PRACTICAL METHOD
ACTIVATION
COMPLEXES
Issue Date: 2013
Publisher: WILEY-V C H VERLAG GMBH
Abstract: A mixed-ligand 3D metal-organic framework, [Ni(1,2-cpd)(bpe)(H2O)]n (1) [1,2-cpd = cis-cyclopentane-1,2-dicarboxylate, bpe = 1,2-di(4-pyridyl)ethylene], has been constructed. Topological analysis revealed that the structure is a 3-c uninodal 2D + 2D 3D polycatenated net with the Schlafli symbol 63. The compound is catalytically active towards the epoxidation reaction in heterogeneous media. It catalyses almost all types of olefinic substrates with equal efficiency. After reaction it can be recovered quite easily and can be used for further reaction without any loss of activity for several cycles. Variable-temperature magnetic susceptibility measurement reveals the presence of a weak antiferromagnetic interaction in compound 1.
Peer review: yes
URI: http://hdl.handle.net/10773/19178
DOI: 10.1002/ejic.201300123
ISSN: 1434-1948
Publisher Version: 10.1002/ejic.201300123
Appears in Collections:CICECO - Artigos



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