Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/18121
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dc.contributor.authorSalonen, Laura M.pt
dc.contributor.authorMedina, Dana D.pt
dc.contributor.authorArgibay, Enrique Carbópt
dc.contributor.authorGoesten, Maarten G.pt
dc.contributor.authorMafra, Luíspt
dc.contributor.authorGuldris, Noeliapt
dc.contributor.authorRotter, Julian M.pt
dc.contributor.authorStroppa, Daniel G.pt
dc.contributor.authorAbreu, Carlos Rodríguezpt
dc.date.accessioned2017-07-26T16:37:16Z-
dc.date.issued2016-
dc.identifier.issn1359-7345pt
dc.identifier.urihttp://hdl.handle.net/10773/18121-
dc.description.abstractA supramolecular strategy based on strongmolecular dipole moments is presented to gain access to covalent organic framework structures with high crystallinity and porosity. Antiparallel alignment of the molecules within the pore walls is proposed to lead to reinforced columnar stacking, thus affording a high-quality material. As a proof of principle, a novel pyrene dione building block was prepared and reacted with hexahydroxytriphenylene to form a boronic ester-linked covalent organic framework. We anticipate the strategy presented herein to be valuable for producing highly defined COF structures.pt
dc.language.isoengpt
dc.publisherRoyal Society of Chemistrypt
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/600375pt
dc.relationinfo:eu-repo/grantAgreement/FCT/UID/CTM/50011/2013pt
dc.relationinfo:eu-repo/grantAgreement/FCT/PTDC/QEQ-QAN/6373/2014pt
dc.relationinfo:eu-repo/grantAgreement/FCT/IF/01401/2013/CP1162/CT0012pt
dc.rightsrestrictedAccesspor
dc.titleA supramolecular strategy based on molecular dipole moments for high-quality covalent organic frameworkspt
dc.typearticle
dc.peerreviewedyespt
ua.distributioninternationalpt
degois.publication.firstPage7986pt
degois.publication.issue51
degois.publication.lastPage7989pt
degois.publication.titleChemical Communicationspt
degois.publication.volume51pt
dc.date.embargo10000-01-01-
dc.identifier.doi10.1039/c6cc02170kpt
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