Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/18110
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dc.contributor.authorMendes, Ricardo F.pt
dc.contributor.authorAntunes, Margarida M.pt
dc.contributor.authorSilva, Patríciapt
dc.contributor.authorBarbosa, Paulapt
dc.contributor.authorFigueiredo, Filipept
dc.contributor.authorLinden, Anthonypt
dc.contributor.authorRocha, Joãopt
dc.contributor.authorValente, Anabela A.pt
dc.contributor.authorPaz, Filipe A. Almeidapt
dc.date.accessioned2017-07-26T14:10:36Z-
dc.date.issued2016-09-
dc.identifier.issn0947-6539pt
dc.identifier.urihttp://hdl.handle.net/10773/18110-
dc.description.abstractA positively charged lamellar coordination polymer based on a flexible triphosphonic acid linker is reported. [Gd(H4nmp)(H2O)2]Cl·2H2O (1) [H6nmp=nitrilotris(methylenephosphonic acid)] was obtained by a one-pot approach by using water as a green solvent and by forcing the inclusion of additional acid sites by employing HCl in the synthesis. Compound 1 acts as a versatile heterogeneous acid catalyst with outstanding activity in organic reactions such as alcoholysis of styrene oxide, acetalization of benzaldehyde and cyclohexanaldehyde and ketalization of cyclohexanone. For all reaction systems, very high conversions were reached (92–97%) in only 15–30 min under mild conditions (35 8C, atmospheric pressure). The coordination polymer exhibits a protonic conductivity of 1.23Õ10¢5 Scm¢1 at 98% relative humidity and 408C.pt
dc.language.isoengpt
dc.publisherWileypt
dc.relationinfo:eu-repo/grantAgreement/FCT/UID/CTM/50011/2013pt
dc.relationinfo:eu-repo/grantAgreement/FCT/EXPL/CTM-NAN/0013/2013pt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/ BD/84231/2012pt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/BD/46601/2008pt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/BPD/89068/2012pt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/BPD/96665/2013pt
dc.relationinfo:eu-repo/grantAgreement/FCT/IF/01174/2013pt
dc.rightsrestrictedAccesspor
dc.titleA lamellar coordination polymer with remarkable catalytic activitypt
dc.typearticle
dc.peerreviewedyespt
ua.distributioninternationalpt
degois.publication.firstPage13136pt
degois.publication.issue37
degois.publication.issue37pt
degois.publication.lastPage13146pt
degois.publication.titleChemistry - A European Journalpt
degois.publication.volume22pt
dc.date.embargo10000-01-01-
dc.identifier.doi10.1002/chem.201602157pt
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