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 Structural and optical characterization of ZnO nanowires grown on alumina by thermal evaporation method
Please use this identifier to cite or link to this item http://hdl.handle.net/10773/6690

title: Structural and optical characterization of ZnO nanowires grown on alumina by thermal evaporation method
authors: Mute, A.
Peres, M.
Peiris, T.C.
Lourenço, A.C.
Jensen, L.R.
Monteiro, T.
keywords: Nanowires
PL
Raman
SEM
Thermal evaporation
ZnO
issue date: 2010
publisher: ASP
abstract: Zinc oxide nanowires have been grown on alumina substrate by thermal evaporation of zinc nanopowder in the presence of oxygen flow. The growth was performed under ambient pressure and without the use of foreign catalyst. Scanning electron microscopy (SEM) observation showed that the as-grown sample consists of bulk ZnO crystal on the substrate surface with nanowires growing from this base. Growth mechanism of the observed morphology is suggested to be governed by the change of zinc vapour supersaturation during the growth process. X-ray diffraction (XRD) measurement was used to identify the crystalline phase of the nanowires. Optical properties of the nanowires were investigated using Raman scattering and photoluminescence (PL). The appearance of dominant, Raman active E2 (high) phonon mode in the Raman spectrum has confirmed the wurtzite hexagonal phase of the nanowires. With above bandgap excitation the low temperature PL recombination is dominated by donor bound exciton luminescence at ~3.37 eV with a narrow full width at half maximum. Free exciton emission is also seen at low temperature and can be observed up to room temperature. The optical data indicates that the grown nanowires have high optical quality.
URI: http://hdl.handle.net/10773/6690
ISSN: 1533-4880
publisher version/DOI: http://dx.doi.org/10.1166/jnn.2010.1386
source: Journal of Nanoscience and Nanotechnology
appears in collectionsFIS - Artigos
I3N - Artigos

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