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 A new supramolecular organic-inorganic adduct: {[Eu(CH(3)OH)(H(2)O)(8)](2) [Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)).2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O)
Please use this identifier to cite or link to this item http://hdl.handle.net/10773/6252

title: A new supramolecular organic-inorganic adduct: {[Eu(CH(3)OH)(H(2)O)(8)](2) [Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)).2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O)
authors: Soares-Santos, Paula C. R.
Cunha-Silva, Luís
Sousa, Filipa L.
Sousa, Joana L. C.
Gates, Paul J.
Klinowski, Jacek
Trindade, Tito
Rocha, João
Cavaleiro, Ana M. V.
Paz, Filipe A. Almeida
Nogueira, Helena I. S.
keywords: Organic–inorganic hybrid crystalline compounds
Polyoxometalate
Crown ether
Europium
issue date: 22-Mar-2011
publisher: Elsevier
abstract: A new europium(III) supramolecular adduct constructed from alpha-Keggin-type [PW(12)O(40)](3-) anions, benzo-15-crown-5 and dibenzo-30-crown-10 molecules, {[Eu(CH(3)OH)(H(2)O)(8)](2)[Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)). 2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O), was prepared and its crystal structure determined by single-crystal X-ray diffraction. The compound was further characterized using FT-IR, FT-Raman and (13)C CP MAS NMR spectroscopy. (c) 2011 Elsevier B.V. All rights reserved.
URI: http://hdl.handle.net/10773/6252
ISSN: 0022-2860
publisher version/DOI: dx.doi.org/10.1016/j.molstruc.2011.01.007
source: Journal of Molecular Structure
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