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 Synthesis and crystal structure of [nBu4N] [Er(pic)(4)] . 5.5H(2)O: a new infrared emitter
Please use this identifier to cite or link to this item http://hdl.handle.net/10773/6027

title: Synthesis and crystal structure of [nBu4N] [Er(pic)(4)] . 5.5H(2)O: a new infrared emitter
authors: Soares-Santos, PCR
Nogueira, HIS
Felix, V
Drew, MGB
Ferreira, RAS
Carlos, LD
Trindade, T
keywords: Erbium complexes
Picolinic acid
Crystal structure
Photoluminescence
issue date: Sep-2003
publisher: Elsevier
abstract: The new erbium(III) complex of picolinic acid (Hpic), [nBu4N][Er(pic)4] 5.5H2O, was synthesized and the crystal structure determined by single-crystal X-ray diffraction. The compound was further characterized using IR, Raman, 1H NMR and elemental analysis. The picolinate ligands (pic ) are coordinated through N,O-chelation to the erbium cations, as shown by X-ray diffraction and spectroscopic results, leading to an eight coordinate complex. Photoluminescence measurements were performed for this compound which exhibits infrared emission.
URI: http://hdl.handle.net/10773/6027
ISSN: 1387-7003
source: Inorganic Chemistry Communications
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