DSpace
 
  Repositório Institucional da Universidade de Aveiro > Departamento de Química > DQ - Artigos >
 Synthesis and Characterization of Poly(2,5-furan dicarboxylate)s Based on a Variety of Diols
Please use this identifier to cite or link to this item http://hdl.handle.net/10773/5527

title: Synthesis and Characterization of Poly(2,5-furan dicarboxylate)s Based on a Variety of Diols
authors: Gomes, M.
Gandini, A.
Silvestre, A. J. D.
Reis, B.
keywords: Aliphatic, aromatic and furan diols
2,5-furandicarboxylic acid
Renewable resources
Crystallinity
Furan polyesters
Thermal properties
Polycondensation
issue date: 2011
publisher: Wiley
abstract: Novel polyesters from renewable resources based on 2,5-dicarboxylic acid and several dials were synthesized and characterized using different polycondensation techniques. The aliphatic dials were sufficiently volatile to allow the use of polytransesterifications, which gave high-molecular weight semicrystalline materials with good thermal stability. In particular, the polyester based on ethylene glycol displayed properties comparable with those of its aromatic counterpart, poly(ethylene terephthalate), namely, the most important industrial polyester. The use of isosorbide gave rise to amorphous polymers with very stiff chains and hence a high glass transition temperature and an enhanced thermal stability. The interfacial polycondensation between the acid dichloride and hydroquinone produced a semicrystalline material with features similar to those of entirely aromatic polyesters, characterized essentially by the absence of melting and poor solubility, both associated with their remarkable chain rigidity. The replacement of hydroquinone with the corresponding benzylic dial was sufficient to provide a more tractable polyester. This study provided ample evidence in favor of the exploitation of furan monomers as renewable alternatives to fossil-based aromatic homologs. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 3759-3768, 2011
URI: http://hdl.handle.net/10773/5527
ISSN: 0887-624X
source: Journal of Polymer Science Part A: Polymer Chemistry
appears in collectionsDQ - Artigos

files in this item

file description sizeformat
J. Polym. Sci. A Chem., 2011, 49, 3759–3768.PDF191.6 kBAdobe PDFview/open
Restrict Access. You can Request a copy!
statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! RCAAP OpenAIRE DeGóis
ria-repositorio@ua.pt - Copyright ©   Universidade de Aveiro - RIA Statistics - Powered by MIT's DSpace software, Version 1.6.2