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 Synthesis and Characterization of Novel Biopolyesters from Suberin and Model Comonomers
Please use this identifier to cite or link to this item http://hdl.handle.net/10773/5181

title: Synthesis and Characterization of Novel Biopolyesters from Suberin and Model Comonomers
authors: Sousa, Andreia F.
Gandini, Alessandro
Silvestre, Armando J. D.
Neto, Carlos Pascoal
keywords: Cork
Polymers
Polymerization
Renewable resources
Suberin
issue date: 2008
publisher: Wiley-VCH Verlag Berlin
abstract: The synthesis of novel polyesters from model long-chain aliphatic monomers and from suberin reactive aliphatic fragments was conducted using mild polycondensation or polytransesterification conditions. The ensuing polyesters were characterized by means of various techniques. When mixtures of simple suberin-like monomers were used, the ensuing polyesters had very regular structures, with melting temperatures around 80 degrees C and glass transitions below room temperature. This first systematic study of the exploitation of suberin as a precursor to novel aliphatic polyesters confirmed the huge potential of using this abundant renewable resource to prepare macromolecular materials for promising applications.
URI: http://hdl.handle.net/10773/5181
ISSN: 1864-5631
publisher version/DOI: http://dx.doi.org/10.1002/cssc.200800178
source: ChemSusChem
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