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http://hdl.handle.net/10773/20751
Title: | Single Crystal to Single Crystal (SC-to-SC) Transformation from a Nonporous to Porous Metal-Organic Framework and Its Application Potential in Gas Adsorption and Suzuki Coupling Reaction through Postmodification |
Author: | Sen, Rupam Saha, Debraj Koner, Subratanath Brandao, Paula Lin, Zhi |
Keywords: | CARBON-DIOXIDE CAPTURE HETEROGENEOUS CATALYTIC EPOXIDATION PALLADIUM(II) COMPLEXES COORDINATION POLYMERS CARBAPALLADACYCLE COMPLEX MESOPOROUS SILICA HYDROGEN-STORAGE HIGHLY EFFICIENT PD NANOPARTICLES HECK REACTIONS |
Issue Date: | 2015 |
Publisher: | WILEY-V C H VERLAG GMBH |
Abstract: | A new amino-functionalized strontium-carboxylate-based metal-organic framework (MOF) has been synthesized that undergoes single crystal to single crystal (SC-to-SC) transformation upon desolvation. Both structures have been characterized by single-crystal X-ray analysis. The desolvated structure shows an interesting 3D porous structure with pendent -NH2 groups inside the pore wall, whereas the solvated compound possesses a nonporous structure with DMF molecules on the metal centers. The amino group was postmodified through Schiff base condensation by pyridine-2-carboxaldehyde and palladium was anchored on that site. The modified framework has been utilized for the Suzuki cross-coupling reaction. The compound shows high activity towards the C-C cross-coupling reaction with good yields and turnover frequencies. Gas adsorption studies showed that the desolvated compound had permanent porosity and was microporous in nature with a BET surface area of 2052 m(2) g(-1). The material also possesses good CO2 (8 wt%) and H-2 (1.87 wt%) adsorption capabilities. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/20751 |
DOI: | 10.1002/chem.201405684 |
ISSN: | 0947-6539 |
Publisher Version: | 10.1002/chem.201405684 |
Appears in Collections: | CICECO - Artigos |
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