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http://hdl.handle.net/10773/19796| Title: | Crystallization-induced light-emission enhancement of diphenylmethane derivatives |
| Author: | Guieu, Samuel Rocha, Joao Silva, Artur M. S. |
| Keywords: | FLUORESCENCE EFFICIENT ACID LUMINESCENCE INHIBITORS |
| Issue Date: | 2013 |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| Abstract: | A family of diphenylmethane derivatives has been synthesized and their luminescence properties characterized. While in solution the compounds are weakly emissive, showing no aggregation-induced emission enhancement, the crystals of three dialkyl 5,5'-methylenebis(2-hydroxybenzoate) samples exhibit intense emission. This emission enhancement upon crystallization is ascribed to particular molecular packing, which stiffens the structure of the compounds via hydrogen bonds, preventing consecutive pi-pi interactions. (C) 2013 Elsevier Ltd. All rights reserved. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/19796 |
| DOI: | 10.1016/j.tet.2013.07.107 |
| ISSN: | 0040-4020 |
| Publisher Version: | 10.1016/j.tet.2013.07.107 |
| Appears in Collections: | CICECO - Artigos |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Crystallization-induced light-emission enhancement of diphenylmethane derivatives_10.1016j.tet.2013.07.107.pdf | 1.38 MB | Adobe PDF |  |
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