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http://hdl.handle.net/10773/19471
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Campo DC | Valor | Idioma |
---|---|---|
dc.contributor.author | Quaresma, Silvia | pt |
dc.contributor.author | Andre, Vania | pt |
dc.contributor.author | Martins, Marta | pt |
dc.contributor.author | Teresa Duarte, M. | pt |
dc.date.accessioned | 2017-12-07T19:13:52Z | - |
dc.date.issued | 2015 | pt |
dc.identifier.issn | 1074-1542 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/19471 | - |
dc.description.abstract | Three different formate-based metal-organic frameworks, [Zn(HCOO) (2) (Bip)], [H (2) N(CH (3) ) (2) ][Zn(HCOO) (3) ] and [Zn (2) (HCOO) (4) (H (2) O) (4) ], were obtained under solvothermal conditions in DMF. [Zn(HCOO) (2) (Bip)] is based on two ligands (formate and 4,4'-bipyridine), while [H (2) N(CH (3) ) (2) ][Zn(HCOO) (3) ] and [Zn (2) (HCOO) (4) (H (2) O) (4) ] only contain the formate ligand. The structural characterization of these compounds shows specific features for each of these networks. Importantly, the work presented herein proves that the formate is a result of DMF decomposition under the acidic solvothermal conditions used, a very relevant point that should be considered when planning solvothermal synthesis of MOFs with organic acids, such as azelaic acid. Three different formate-based metal-organic frameworks were obtained under solvothermal conditions in DMF. Structural characterization of these compounds shows specific features for each of these networks. The formate is a result of DMF decomposition under the acidic solvothermal conditions used. [GRAPHICS] . | pt |
dc.language.iso | eng | pt |
dc.publisher | SPRINGER/PLENUM PUBLISHERS | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/3599-PPCDT/122447/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/3599-PPCDT/132962/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F78854%2F2011/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/5876/147332/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | COORDINATION POLYMERS | pt |
dc.subject | DRUG-DELIVERY | pt |
dc.subject | DICARBOXYLIC-ACIDS | pt |
dc.subject | CARBON-DIOXIDE | pt |
dc.subject | AZELAIC ACID | pt |
dc.subject | HYDROGEN | pt |
dc.subject | NETWORKS | pt |
dc.subject | PYRIDINEDICARBOXYLATE | pt |
dc.subject | CRYSTALLOGRAPHY | pt |
dc.subject | OXALATE | pt |
dc.title | Zinc-Formate Metal-Organic Frameworks: Watch Out for Reactive Solvents | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 178 | pt |
degois.publication.issue | 4 | pt |
degois.publication.lastPage | 188 | pt |
degois.publication.title | JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | pt |
degois.publication.volume | 45 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1007/s10870-015-0578-y | pt |
dc.identifier.doi | 10.1007/s10870-015-0578-y | pt |
Aparece nas coleções: | CICECO - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Zinc-Formate Metal-Organic Frameworks Watch Out for Reactive Solvents_10.1007s10870-015-0578-y.pdf | 2.55 MB | Adobe PDF |
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